CAS 13965-03-2 Bis(triphenylphosphine)palladium(II) chloride CAS NO.13965-03-2

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CAS NO.13965-03-2
Other Names:Palladium(II)bis(triphenylphosphine) dichloride
MF:C36H30Cl2P2Pd
EINECS No.:237-744-2
Place of Origin: Wuhan
Type:Syntheses Material Intermediates
Purity:99.0%min
Brand Name:JDCHEM
Application:Catalyst
Appearance:Yellow crystal
Form:crystal 
Molecular Weight:701.91
M.P.:260℃
B.P.:360 °C at 760 mmHg
Refractive Index:-
Flash Point:181.7 °C
Water solubility:insoluble
COA/MSDS:Available
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Keywords: triphenylphosphine，palladium，Dichlorobis，

Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Bis(triphenylphosphine)palladium(II) dichloride was employed in the following studies:
1. As model catalyst for the evaluation of functionalized silica′s for the adsorptive recovery of homogeneous catalysts, via its interaction with metal centre.
2. As catalyst in the synthesis of diphenylacetylene.
3. One-pot synthesis of furoquinolines, via Pd-catalyzed Sonogashira coupling followed by Cu(I) catalyzed ring closure.
4. Catalyst for Sonogashira coupling of aryl alkynes to 2-bromothiazole and 2-bromothiophene.

General description
Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction. Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported. It is employed as catalyst for the Heck reaction medium.